INFLUENCE OF RADIONUCLIDES ON MOLECULAR DYNAMICS OF FUNCTIONAL GROUPS OF CAPER PRICKLY

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Authors: Umarov Nasimjon Negmatovich - Candidate of Physical and Mathematical Sciences, Associate Professor of the Department of Theoretical Physics and the MTPh of the PEI “KSU named after academic Bobojon Gafurov”, Yusupov Izatullo Khodzhaevich - Сandidate of Physical and Mathematical Sciences, Head of the Laboratory of Molecular Spectroscopy, Physico-technical Institute named after S.U. Umarova NANT, Abdumanonov Abduali - Doctor of Physical and Mathematical Sciences, Professor, the Head Physics Laboratory in Khujand Science Center NANT, Kadirov Abdulakhat Lakimovich - Doctor of Physical and Mathematical Sciences, Professor of the Department of Electronics of the PEI “KSU named after academic Bobojon Gafurov”, Abdullaev Sabur Fuzailovich - Doctor of Physical and  Mathematical Sciences, Professor, Head  of Atmospheric Physics Laboratory S.U. Umarov Physical Technical Institute National Academy of Sciences of the Republic of Tajikistan

 

JOURNAL NUMBER: 3(58). YEAR OF ISSUE2021. LANGUAGE OF THE ARTICLE: Russian

 

ANNOTATION

Using a gamma-radiometric method that one of spin bores, the effect of radionuclides on rotational mobility of the formers attached to hydroxyl groups of prickly caper paragons of plants was studied. It has been established that radionuclides contribute to an increase of rotational mobility of spin bores. It is found out that at room temperature in the modified samples there happen retardation of the spin label motions with a correlation time τc ≤ 10с-8 and, in general, the electron paramagnetic resonance specters become narrower, indicating an to increase in the mobility of a nitroxyl fragment. The result of IR-spectroscopy analysis it was revealed that by interaction of the plant with a radionuclide there takes place an alteration of the state of maximums relating to the stripes absorbing valency vacillations of functional groups ОН, СН, СН2 and others. It was found that the energy of intermolecular interactions of hydroxyl groups decreases, as it is evidenced by the shift of the absorption stripes maximum into the plot with low frequency (20–40 cm-1).

 

 

KEY WORDS

radionuclides, spectroscopy, spin bore, rotational mobility, vibration of functional groups.